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null (Ed.)V 2 O 5 is of interest as a Mg intercalation electrode material for Mg batteries, both in its thermodynamically stable layered polymorph (α-V 2 O 5 ) and in its metastable tunnel structure (ζ-V 2 O 5 ). However, such oxide cathodes typically display poor Mg insertion/removal kinetics, with large voltage hysteresis. Herein, we report the synthesis and evaluation of nanosized ( ca . 100 nm) ζ-V 2 O 5 in Mg-ion cells, which displays significantly enhanced electrochemical kinetics compared to microsized ζ-V 2 O 5 . This effect results in a significant boost in stable discharge capacity (130 mA h g −1 ) compared to bulk ζ-V 2 O 5 (70 mA h g −1 ), with reduced voltage hysteresis (1.0 V compared to 1.4 V). This study reveals significant advancements in the use of ζ-V 2 O 5 for Mg-based energy storage and yields a better understanding of the kinetic limiting factors for reversible magnesiation reactions into such phases.more » « less
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Yoo, Hyun Deog; Jokisaari, Jacob R.; Yu, Young-Sang; Kwon, Bob Jin; Hu, Linhua; Kim, Soojeong; Han, Sang-Don; Lopez, Mario; Lapidus, Saul H.; Nolis, Gene M.; et al (, ACS Energy Letters)
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